Oxygen vacancy-expedited ion diffusivity in transition-metal oxides for high-performance lithium-ion batteries

نویسندگان

چکیده

Rapid capacity decay and inferior kinetics are the vital issues of anodes in conversion reaction for lithium-ion batteries. Vacancy engineering can efficiently modulate intrinsic properties transition-metal oxide (TMO)-based electrode materials, but effect oxygen vacancies on performance remains unclear. Herein, abundant situ introduced into lattice different TMOs (e.g., Co3O4, Fe2O3, NiO) via a facile hydrothermal treatment combined with calcination. Taking Co3O4 as typical example, results prove that Co3O4−x effectively accelerate charge transfer at interface significantly increase electrical conductivity pseudocapacitance contribution. The Li-ion diffusion coefficient is remarkably improved by two orders magnitude compared Co3O4. Theoretical calculations reveal has lower Li-insertion energy barrier more density states around Fermi level than which favorable ion electron transport. Therefore, rich exhibit superior cycling enhanced rate capability over their counterparts. This strategy regulating would provide inspiration designing other TMO-based electrodes applications.

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ژورنال

عنوان ژورنال: Science China. Materials

سال: 2022

ISSN: ['2095-8226', '2199-4501']

DOI: https://doi.org/10.1007/s40843-021-1909-5